Synthesis and structure of distanna and tristanna ansa half-sandwich complexes of ruthenium and nickel |
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| Authors: | Braunschweig Holger Dörfler Rainer Hammond Kai Kramer Thomas Mies Jan Radacki Krzysztof Schäfer Marius |
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| Affiliation: | Institut für Anorganische Chemie, Universit?t Würzburg, Am Hubland, D-97074 Würzburg, Germany. h.braunschweig@uni-wuerzburg.de |
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| Abstract: | The synthesis and structural characterization of the first tin-bridged ansa half-sandwich complexes via a two-step protocol from Na[η(5)-C(5)H(5)Ru(CO)(2)] and in situ generated Na[η(5)-C(5)H(5)Ni(CO)] are presented. Both compounds are characterized by multinuclear NMR spectroscopy and single-crystal diffraction. |
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