Ruthenium catalyzed synthesis of enaminones |
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| Authors: | Koduri Naga Durgarao Scott Halee Hileman Bethany Cox Justin D Coffin Michael Glicksberg Lindsay Hussaini Syed R |
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| Institution: | Department of Chemistry and Biochemistry, The University of Tulsa, Keplinger Hall, 800 South Tucker Drive, Tulsa, Oklahoma 74101, USA. |
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| Abstract: | The Grubbs first-generation catalyst has been found to be an effective catalyst for the synthesis of enaminones by coupling thioamides with α-diazodicarbonyl compounds. The reaction is successful in converting primary, secondary, and tertiary thioamides into their corresponding enaminones. The reaction is also suitable for the synthesis of chiral enaminones. |
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