| 氯化环戊二烯三羰基钼(钨)与β-环糊精超分子化合物的合成和表征 |
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| 引用本文： | 张有明,魏太保.氯化环戊二烯三羰基钼(钨)与β-环糊精超分子化合物的合成和表征[J].无机化学学报,2002,18(9):921-923. |
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| 作者姓名： | 张有明 魏太保 |
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| 作者单位： | 西北师范大学化学系,兰州,730070 |
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| 基金项目： | 国家自然科学基金资助项目(No.29971026)，西北师大知识与科技创新工程项目(No.02-18)。 |
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| 摘 要： | Two new kinds of supramolecular inclusion compound of β-cyclodextrin(host)and chloro-cyclopentadi- enyl-tricarbonyl-molybdenum(tungsten)(guest) have been prepared and characterized by using the chemical ele-mental analyses, infrared spectroscopy, nuclear magnetic resonance,powder X-ray diffractometry and thin-layer chromatography(TLC). The results show that β-CD formed one-to-one compounds with guest and the cyclopenta-dienyl group of guest may be included into the hydrophobic cavity of β-CD. Differential thermal analyses reveal that after formation of the supramolecular inclusion compounds, thermal stability of the host and guest molecules in-creased.
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| 关 键 词： | 羰基过渡金属配合物 β-环糊精 超分子 |
| 修稿时间： | 2002年3月20日 |
Syntheses and Characterization of Chloro-Cyclopentadienyl-Tricarbonyl-Molybdenum (Tungsten)/β-CD Supramolecules |
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| ZHANG You-Ming and WEI Tai-Bao.Syntheses and Characterization of Chloro-Cyclopentadienyl-Tricarbonyl-Molybdenum (Tungsten)/β-CD Supramolecules[J].Chinese Journal of Inorganic Chemistry,2002,18(9):921-923. |
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| Authors: | ZHANG You-Ming and WEI Tai-Bao |
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| Institution: | Department of Chemistry,Northwest Normal University, Lanzhou 730070 and Department of Chemistry,Northwest Normal University, Lanzhou 730070 |
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