Protection of the amino group of adenosine and guanosine derivatives by elaboration into a 2,5-dimethylpyrrole moiety |
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| Authors: | Nowak Ireneusz Robins Morris J |
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| Affiliation: | Department of Chemistry and Biochemistry, Brigham Young University, Provo, Utah 84602-5700, USA. |
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| Abstract: | [reaction: see text] Protection of the amino group of adenine and guanine nucleosides was effected by heating the substrates in 2,5-hexanedione. The resulting 2,5-dimethylpyrrole adducts were stable toward bases but were hydrolyzed with TFA/H(2)O to regenerate the amino function. |
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