| PYRIDINATION OF POLY（VINYL CHLORIDE） via A HOMOLYTIC PATHWAY |
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| 引用本文： | Saad Moulay Zakia Zeffouni. PYRIDINATION OF POLY（VINYL CHLORIDE） via A HOMOLYTIC PATHWAY[J]. 高分子科学, 2007, 0(3): 297-302 |
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| 作者姓名： | Saad Moulay Zakia Zeffouni |
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| 作者单位： | Laboratoire de Chimie-Physique Moléculaire et Macromoléculaire Faculté des Sciences de l'Ingénieur Département de Chimie Industrielle，Université Sad Dahlab de Blida，Route de Souma，B. P. 270，Blida 09000，Algeria，Laboratoire de Chimie-Physique Moléculaire et Macromoléculaire Faculté des Sciences de l'Ingénieur，Département de Chimie Industrielle，Université Sad Dahlab de Blida，Route de Souma，B. P. 270，Blida 09000，Algeria |
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| 摘 要： | PVC was subjected to a chemical modification aiming at replacing the chlorine atoms by pyridine groups via a homolytic route. Pyridine groups were peculiarly affixed to the PVC matrix via a carbon-carbon bond rather than a carbon-nitrogen one. PVC was first iodinated using the Conant-Finkelstein reaction, followed by the application of the homolytic conditions of Minisci to generate pyridinated PVC with a varying degree of substitution. The extent of substitution was not high; the reaction on 30% iodinated PVC afforded a degree of modification no greater than 3%.
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| 关 键 词： | PVC 化学改性 碘处理 吡啶处理 均裂反应路线 |
| 收稿时间： | 2006-06-08 |
| 修稿时间： | 2006-07-06 |
PYRIDINATION OF POLY(VINYL CHLORIDE) via A HOMOLYTIC PATHWAY |
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| Sa,acirc,d Moulay,Zakia Zeffouni. PYRIDINATION OF POLY(VINYL CHLORIDE) via A HOMOLYTIC PATHWAY[J]. Chinese Journal of Polymer Science, 2007, 0(3): 297-302 |
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| Authors: | Saâ d Moulay Zakia Zeffouni |
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| Affiliation: | Laboratoire de Chimie-Physique Moléculaire et Macromoléculaire Faculté des Sciences de l’Ingénieur, Département de Chimie Industrielle, Université Saâd Dahlab de Blida, Route de Soumâa, B. P. 270, Blida 09000, Algeria |
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| Abstract: | PVC was subjected to a chemical modification aiming at replacing the chlorine atoms by pyridine groups via a homolytic route. Pyridine groups were peculiarly affixed to the PVC matrix via a carbon-carbon bond rather than a carbonnitrogen one. PVC was first iodinated using the Conant-Finkelstein reaction, followed by the application of the homolytic conditions of Minisci to generate pyridinated PVC with a varying degree of substitution. The extent of substitution was not high; the reaction on 30% iodinated PVC afforded a degree of modification no greater than 3%. |
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| Keywords: | Conditions of Minisci Iodinated PVC Pyridinated PVC POLY CHLORIDE VINYL degree of substitution chemical modification extent high application conditions generate reaction matrix bond rather chlorine atoms pyridine groups route |
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