Abstract: | CuK2H2(PCrO7)2 is monoclinic, P21/c, with a unit cell: a=9.559(5)Å; b=7.196(5)Å; c=8.983(5)Å;β=93.73(5)°; Z=2; and D=2.87g/cm3.The crystal structure of this compound has been resolved by using 1938 independent reflections with a final R value of 0.03. The main feature of this compound is the existence of the mixed pyro-group CrPO7, up to now the first to be described. |