Liquid-liquid extraction and spectrophotometric determination of uranium with n-phenyl-3-styrylacrylohydroxamic acid (PSAHA) |
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| Authors: | Y K Agrawal D B Upadhyaya S P Chudasama |
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| Institution: | (1) Department of Chemistry, School of Sciences, Gujarat University, Navrangpura, 380 009 Ahmedabad, (India);(2) Chemistry Department, University of Bahrain, P.O. Box 32038, Isa Town (Bahrain) |
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| Abstract: | A rapid, selective and sensitive liquid-liquid extraction and spectrophotometric method for the separation and microgram determination of uranium using PSAHA is described. Uranium is extracted with PSAHA into chloroform at pH 6.0–6.8. The U-PSAHA chelate is orange red in color having maximum absorbance at 410 nm and molar absorptivity 1.2·104l·mol–1·cm–1. The system obeys Beer's Law in the range of 1.2 to 22.00 ppm of uranium. The uranium is determined in sea water and rock samples. |
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