| 多蝶烯及其衍生物的合成与应用进展 |
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| 引用本文： | 曹菁,江一,陈传峰. 多蝶烯及其衍生物的合成与应用进展[J]. 化学进展, 2011, 23(11): 2200 |
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| 作者姓名： | 曹菁 江一 陈传峰 |
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| 作者单位： | 北京分子科学国家实验室 中国科学院化学研究所 分子识别与功能重点实验室 北京 100190 |
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| 基金项目： | 国家自然科学基金项目(No.20625206,20772126); 国家重大科学研究计划项目(No.2011CB932501)资助 |
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| 摘 要： | 多蝶烯及其衍生物是一类具有独特三维刚性结构的芳香族化合物,它们由三个以上的独立苯环连接在 双环辛三烯片段上而形成,多蝶烯的概念是对三蝶烯概念的扩展。近年来,由于其特殊的刚性、芳香性以及三维骨架结构,该类化合物引起了人们越来越多的关注,并在超分子化学、材料化学、分子机器等许多领域得到了越来越广泛的应用。本文首先概述多蝶烯、多蝶烯醌及其衍生物的合成,然后重点介绍多蝶烯衍生物在共轭聚合物材料、有机多孔与低介电常数材料、化学传感、单层自组装结构、分子机器以及基于新型合成主体超分子化学等方面的应用研究进展。
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| 关 键 词： | 多蝶烯 合成 应用 主体 超分子化学 |
| 收稿时间： | 2011-06-01 |
Advances on Synthesis and Applications of Iptycenes and Their Derivatives |
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| Cao Jing Jiang Yi Chen Chuan-Feng. Advances on Synthesis and Applications of Iptycenes and Their Derivatives[J]. Progress in Chemistry, 2011, 23(11): 2200 |
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| Authors: | Cao Jing Jiang Yi Chen Chuan-Feng |
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| Affiliation: | Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China |
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| Abstract: | Iptycenes and their derivatives are a class of structurally unique compounds consisting of more than three arene units fused together through a bicyclooctatriene framework.Iptycene is also extended triptycene,and it can be named after the number of arene planes separated by a bridgehead system.Pentiptycenes with five arene units are the most common members of iptycenes,and pentiptycene quinones are the most studied iptycene derivatives.Since they possess a rigid,aromatic,and three dimensional scaffold,iptyc... |
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| Keywords: | iptycene synthesis application host supramolecular chemistry |
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