Aryl trihydroxyborates: easily isolated discrete species convenient for direct application in coupling reactions |
| |
| Authors: | Cammidge Andrew N Goddard Victoria H M Gopee Hemant Harrison Nicola L Hughes David L Schubert Christopher J Sutton Benjamin M Watts Gary L Whitehead Andrew J |
| |
| Affiliation: | School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich NR4 7TJ, U.K. a.cammidge@uea.ac.uk |
| |
| Abstract: | A conceptually and practically simple alternative approach to the use of arylboron species as the organometallic component in cross-coupling processes is described whereby trihydroxyborate salts are isolated and directly employed. The protocol derives practical benefit from the ease and convenience of the isolation and subsequent use of the discrete borate salts, eliminates the need for additional base, and aids the use of correct reaction stoichiometry. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
