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Effect of ion irradiation on C 60 thin films
Authors:K. Narumi   Y. Xu   K. Miyashita  H. Naramoto
Affiliation:(1) Takasaki Branch, Advanced Science Research Center, Japan Atomic Energy Research Institute, 1233 Watanuki-machi, Takasaki, Gunma 370-1292, Japan;(2) Gunma Prefectural Industrial Technology Research Laboratory, 190 Toriba-machi, Maebashi, Gunma 371-0845, Japan
Abstract:We report a new effect of ion irradiation onC60 thin films:C60 thin films irradiated with 7-MeVC2+ ions show resistance tophotopolymerization. The resistance increases with increasingion fluence of irradiation. The effect is qualitativelyexplained by the fact that the number of aC60 pair satisfying the topochemicalrequirement for photochemical reaction in solids decreases bydestruction of C60 molecules accompaniedby lattice disorder.
Keywords:61.48.+c Fullerenes and fullerene-relatedmaterials  61.80.Jh Ion radiation effects  82.35.-x Polymers:properties   reactions   polymerization
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