| Dramatic Solvent Effect in the Reduction of 2,3—Allenoic Acid Esters.A Simple Synthesis of 2,3—Allenols from 2,3—Allenoates |
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| 引用本文： | YIN，Shao－Hu MA，Sheng－Ming 等. Dramatic Solvent Effect in the Reduction of 2,3—Allenoic Acid Esters.A Simple Synthesis of 2,3—Allenols from 2,3—Allenoates[J]. 中国化学, 2002, 20(7): 707-710. DOI: 10.1002/cjoc.20020200717 |
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| 作者姓名： | YIN，Shao－Hu MA，Sheng－Ming 等 |
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| 作者单位： | DepartmentofChemistry,FudanUniversity,Shanghai200433,China |
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| 基金项目： | ProjectsupportedbytheMajorStateBasicResearchDevelopmentProgram (No .G2 0 0 0 0 775 0 0 )，theNationalNaturalScienceFounda tionofChina，andShanghaiMunicipalCommitteeofScienceandTechnology . |
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| 摘 要： | 2，3－Allenols were prepared conveniently from the reduction reaction of 2,3-allenoates with DIBAL-H(Diisobutylaluminum hydride) in toluene.A dramatic solvent effect was observed for this reaction.
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| 关 键 词： | 还原反应 丙二烯酸酯 2，3－丙二酮 溶剂效应 2，3－丙二烯酸盐 |
Dramatic Solvent Effect in the Reduction of 2,3‐Allenoic Acid Esters. A Simple Synthesis of 2,3‐Allenols from 2,3‐Allenoates |
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| Shao‐Hu Yin,Sheng‐Ming Ma,Ning Jiao,Feng‐Gang Tao. Dramatic Solvent Effect in the Reduction of 2,3‐Allenoic Acid Esters. A Simple Synthesis of 2,3‐Allenols from 2,3‐Allenoates[J]. Chinese Journal of Chemistry, 2002, 20(7): 707-710. DOI: 10.1002/cjoc.20020200717 |
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| Authors: | Shao‐Hu Yin Sheng‐Ming Ma Ning Jiao Feng‐Gang Tao |
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| Abstract: | 2,3‐Allenols were prepared conveniently from the reduction reaction of 2, 3‐allenoates with DIBAL‐H (Diisobutylaluminum hydride) in toluene. A dramatic solvent effect was observed for this reaction. |
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| Keywords: | 2,3‐allenoates reduction 2,3‐allenols |
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