Photodimerizable ditopic ligand |
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| Authors: | Jouvenot Damien Glazer Edith C Tor Yitzhak |
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| Institution: | Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, 92093, USA. |
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| Abstract: | reaction: see text] The synthesis, photophysical properties, and structural characterization of a photodimerizable ditopic ligand are described. Upon irradiation at 366 nm, ligand 1 dimerizes to the head-to-tail tetra-bpy ligand 2. This thermally stable photodimer can be dissociated back to 1 using higher energy irradiation (254 nm). |
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