Kinetic stability of tetra(3-nitro-5-tert-butyl)phthalocyanine in the system nitrogen-containing base-DMSO |
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| Authors: | O. A. Petrov G. V. Osipova E. L. Kuz’mina |
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| Affiliation: | 1.Ivanovo State University of Chemical Technology,Ivanovo,Russia |
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| Abstract: | The state of tetra(3-nitro-5-tert-butyl)phthalocyanine in DMSO medium was studied. Sufficiently high stability of the obtained proton transfer complex is established, and its structure is suggested. It is shown that this complex is kinetically unstable in the highly basic media. Effect of the nature of cyclic and acyclic nitrogen-containing bases on the rate and activation parameters of destruction of the proton transfer complex of tetra(3-nitro-5-tert-butyl)phthalocyanine was found |
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