| 吡嗪-2,3,5,6-四甲酸镍配合物[Ni(ptcH2)(bpy)(H2O)]的水热合成、结构及性质 |
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| 引用本文： | 杨爱红,房素荣,张燕平,高洪苓,崔建中.吡嗪-2,3,5,6-四甲酸镍配合物[Ni(ptcH2)(bpy)(H2O)]的水热合成、结构及性质[J].无机化学学报,2008,24(3):487-490. |
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| 作者姓名： | 杨爱红 房素荣 张燕平 高洪苓 崔建中 |
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| 作者单位： | 天津大学化学系,天津,300072 |
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| 摘 要： | A complex of nickel(Ⅱ) with pyrazine-2,3,5,6-tetracarboxylic acid and 2,2′-bipyridine, Ni(ptcH2)(bpy)(H2O)], was synthesized by hydrothermal reaction of Ni(NO3)2·6H2O with pyrazine-2,3,5,6-tetracarboxylic acid and 2,2′-bipyridine at 160 ℃ and characterized by elemental analysis, IR and X-ray diffraction single crystal structure determined. The crystal belongs to Monoclinic system, with space group P21/c, a=1.327 9(7) nm, b=1.279 7(7) nm, c=1.161 4(7) nm; β=113.435(8)°, V=1.810 6(17) nm3, Z=4. The coordination environment of nickel(Ⅱ) ion is a distorted octahedral geometry. The title complex is a mononuclear structure which is assembled into 3D supramolecular architecture by strong hydrogen bonds. CCDC: 661507.
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| 关 键 词： | 镍配合物 吡嗪-2，3，5，6-四甲酸 氢键 脱羧 |
| 文章编号： | 1001-4861(2008)03-0487-04 |
| 收稿时间： | 2007/10/10 0:00:00 |
| 修稿时间： | 2007年10月10 |
Hydrothermal Synthesis, Crystal Structure and Properties of a Nickel (H) Complex of Pyrazine-2,3,5,6-tetracarboxylic Acid |
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| YANG Ai-Hong,FANG Su-Rong,ZHANG Yan-Ping,GAO Hong-Ling and CUI Jian-Zhong.Hydrothermal Synthesis, Crystal Structure and Properties of a Nickel (H) Complex of Pyrazine-2,3,5,6-tetracarboxylic Acid[J].Chinese Journal of Inorganic Chemistry,2008,24(3):487-490. |
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| Authors: | YANG Ai-Hong FANG Su-Rong ZHANG Yan-Ping GAO Hong-Ling and CUI Jian-Zhong |
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| Institution: | Department of Chemistry, Tianjin University, Tianjin 300072,Department of Chemistry, Tianjin University, Tianjin 300072,Department of Chemistry, Tianjin University, Tianjin 300072,Department of Chemistry, Tianjin University, Tianjin 300072 and Department of Chemistry, Tianjin University, Tianjin 300072 |
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| Abstract: | |
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| Keywords: | nickel complex pyrazine-2 3 5 6-tetracarboxylic acid hydrogen bonds decarboxylation |
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