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On the Wigner-Witmer correlation rules for a homonuclear diatomic molecule with the like atoms in identical atomic states
Authors:V. P. Bellary   T. K. Balasubramanian  B. J. Shetty
Affiliation:(1) Spectroscopy Division, Bhabha Atomic Research Centre, 400 085 Trombay, Mumbai, India
Abstract:The problem of building the manifold of electronic states of a homonuclear diatomic molecule formed from two like atoms in identical atomic states is readdressed. A conceptually simple approach is presented by invoking a model and all the standard results originally obtained by Wigner and Witmer are reproduced.
Keywords:Homonuclear molecules  Wigner-Witmer rules  diatomic states
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