Change in the size dependences of the surface properties of nanodiamond upon variation in the isotope composition

The isothermal-isomorphic dependences of the specific surface energy (σ), its isochoric temperature derivative (σ′), and surface pressure (P _sf) on the size of nanodiamonds ¹²C and ¹³C at 100 and 4300 K are calculated. It is shown that the ratio σ(¹²C)/σ(¹³C) decreases with decreasing size along both isotherms, and σ′(¹²C)/σ′(¹³C) increases with decreasing size, and this effect is higher at lower temperatures. The ratio P _sf(¹²C)/P _sf(¹³C) increases with decreasing size. The effect is stronger at higher temperatures.