Spontaneous asymmetric crystallization of a quartz-type framework from achiral precursors |
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| Authors: | Zheng Wenxu Wei Yongqin Xiao Xueying Wu Kechen |
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| Institution: | State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P R China. |
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| Abstract: | An enantioenriched three-dimensional quartz-type framework {Ni(1.5)(tzdc)(H(2)O)(3)]·3H(2)O}(n) (H(3)tzdc = 4H-1,2,4-triazole-3,5-dicarboxylic acid) possessing chiral channels is obtained through spontaneous asymmetric crystallization without any enantiopure additive. |
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