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Additional Y3+ Doping Effect on Ferromagnetism of Ce0.97Co0.03O2-δ Compounds
作者姓名:宋远强 张怀武 文岐业 朱豪 肖强
作者单位:[1]State Key Laboratory of Electronic Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 [2]Department of Physics and Astronomy, University of Delaware, Newark, DE 19716, USA
基金项目:Supported by the National Basic Research Programme of China under Grant No 2007CB31407, and the International S&T Cooperation Programme of China under Grant No 2006DFA53410.
摘    要:Y^3+ doping effect on magnetic properties of Ce0.97Co0.03O2-δ are examined. Vibrating sample magnetometer (VSM) measurements indicate that Ce0.97Co0.03O2-δ is ferromagnetic at room temperature. The saturated magnetization Ms is altered by additional Y^3+ doping, i.e., with the increase of the amount of Y^3+ doping concentration in Ce0.97-yYyCo0.03O2-δ(y = 0.01, 0.05 and 0.10), Ms increases persistently, Raman spectra measurements indicate that additional oxygen vacancies are introduced with the amount of Y^3+ doping content. The results can be well elucidated by the F-centre exchange coupling (FCE) mechanism proposed recently, thus they are important for understanding the ferromagnetism origination in transitional metal-doped insulating oxides.

关 键 词:铁磁性 Ce0.97Co0.03O2-δ 复合物 杂质
收稿时间:2007-12-27
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