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Gas-Phase Electron Diffraction and Quantum-Chemical Studies of the Molecular Structure of N,N-dimethyldiaziridine |
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| Authors: | E G Atavin A V Golubinskii M V Popik V V Kuznetsov N N Makhova A V Anikeeva L V Vilkov |
| Institution: | 1. Omsk State University, Russia 2. M. V. Lomonosov Moscow State University, Russia 3. N. D. Zelinskii Institute of Organic Chemistry, Moscow |
| Abstract: | Molecular structure of N,N-dimethyldiaziridine was studied by gas-phase electron diffraction and quantum-chemical methods. It is confirmed that the molecule has a trans conformation, but the structural parameters r(endo-C–N) 1.448(2) Å, r(exo-C–N) 1.468(2) Å, and r(N–N) 1.514(6) Å differ substantially from the results of our previous electron diffraction study. |
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