Enantioselective manganese-porphyrin-catalyzed epoxidation and C-H hydroxylation with hydrogen peroxide in water/methanol solutions |
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| Authors: | Srour Hassan Le Maux Paul Simonneaux Gerard |
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| Institution: | Institute of Sciences Chimiques of Rennes, Ingénierie Chimique et Molécules pour le vivant UMR 6226 CNRS, Campus de Beaulieu, 35042 Rennes cedex, France. |
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| Abstract: | The asymmetric epoxidation of alkene and hydroxylation of arylalkane derivatives by H(2)O(2) to give optically active epoxides (enantiomeric excess (ee) up to 68%) and alcohols (ee up to 57%), respectively, were carried out in water/methanol solutions using chiral water-soluble manganese porphyrins as catalysts. |
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