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Oxidation of bis(Trimethylsilyl)amidodifluorophosphite
Authors:S. A. Lermontov  N. V. Sukhova  I. V. Martynov
Affiliation:(1) Institute of Physiologically Active Compounds, Academy of Sciences of the USSR, Chernogolovka
Abstract:Conclusions The reaction of tert-butyl hypochlorite with bis(trimethylsilyl)amidodifluorophosphite gives an intermediate quasiphosphonium salt, which decomposes losing either the trimethylsilyl group or tert-butyl group with equal probability.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1426–1428, June, 1989.
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