Oxidation of bis(Trimethylsilyl)amidodifluorophosphite |
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Authors: | S. A. Lermontov N. V. Sukhova I. V. Martynov |
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Affiliation: | (1) Institute of Physiologically Active Compounds, Academy of Sciences of the USSR, Chernogolovka |
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Abstract: | Conclusions The reaction of tert-butyl hypochlorite with bis(trimethylsilyl)amidodifluorophosphite gives an intermediate quasiphosphonium salt, which decomposes losing either the trimethylsilyl group or tert-butyl group with equal probability.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1426–1428, June, 1989. |
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