Conversion of ascorbigen and its derivatives to substituted 1-deoxy-1-(indolyl-3)-α-L-sorbopyranose |
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| Authors: | I. L. Plikhtyak I. V. Yartseva N. A. Klyuev M. N. Preobrazhenskaya |
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| Affiliation: | (1) All-Union Oncologic Research Center, Academy of Medical Sciences of the USSR, 115478 Moscow;(2) A. N. Severtsova Institute of Evolutionary Morphology and Ecology of Animals, Academy of Sciences of the USSR, 117071 Moscow |
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| Abstract: | A new reaction involving L-ascorbic acid have been found. Under the action of alkali, ascorbigen and its N-alkyl derivatives undergo cleavage of the lactone ring, decarboxylation, and rearrangement to give 1-deoxy-1-(inolyl-3)- -L-sorbopyranose and its N-alkyl derivatives. The structures of the compounds obtained were confirmed by mass-spectroscopy and PMR spectroscopy.Translated from Khimiko Geterotsiklicheskikh Soedinenii, No. 5, pp. 607–610, May, 1989. |
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