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磁性Fe3O4 /壳聚糖的化学修饰及包覆机理研究
引用本文:黄可龙,陈 洁,刘素琴,李桂银.磁性Fe3O4 /壳聚糖的化学修饰及包覆机理研究[J].无机化学学报,2007,23(8):1491-1495.
作者姓名:黄可龙  陈 洁  刘素琴  李桂银
作者单位:中南大学化学化工学院,长沙,410083
基金项目:国家自然科学基金;中南大学校科研和教改项目
摘    要:Nano-sized Fe3O4 powder was prepared through an Oxygenation-Hydrothermal method. The chitosan magnetic complex was prepared by coating chitosan on the surface of Fe3O4 powders through Microlatex-Crosslinking Method. The product was characterized by IR, XRD, TEM, Vibrating Sample Magnetometer (VSM), TG methods. Results show that the as-prepared powder is 25 nm in size and shows supermagnetism. The content of magnetite in microspheres is 37.8%. The mechanism for the coating reaction of chitosan to Fe3O4 nanoparticles is also suggested.

关 键 词:Fe3O4    壳聚糖    包覆    机理
文章编号:1001-4861(2007)08-1491-05
修稿时间:2007-04-162007-06-18

Chemical Modification and Coating Mechanism of Magnetic Fe3O4 /Chitosan
HUANG Ke-Long,CHEN Jie,LIU Su-Qin and LI Gui-Yin.Chemical Modification and Coating Mechanism of Magnetic Fe3O4 /Chitosan[J].Chinese Journal of Inorganic Chemistry,2007,23(8):1491-1495.
Authors:HUANG Ke-Long  CHEN Jie  LIU Su-Qin and LI Gui-Yin
Abstract:Nano-sized Fe3O4 powder was prepared through an Oxygenation-Hydrothermal method. The chitosan magnetic complex was prepared by coating chitosan on the surface of Fe3O4 powders through Microlatex-Crosslinking Method. The product was characterized by IR,XRD,TEM,Vibrating Sample Magnetometer (VSM),TG methods. Results show that the as-prepared powder is 25 nm in size and shows supermagnetism. The content of magnetite in microspheres is 37.8%. The mechanism for the coating reaction of chitosan to Fe3O4 nanoparticles is also suggested.
Keywords:Fe3O4  chitosan  coat  mechanism
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