| FeCl3催化的溴代芳烃与取代硫酚的偶联：合成二芳基硫醚 |
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| 引用本文： | 李龙彪,吴剑娇,陈仁尔,周其忠,徐土根,蒋华江.FeCl3催化的溴代芳烃与取代硫酚的偶联：合成二芳基硫醚[J].浙江大学学报(理学版),2012,39(3):313-316. |
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| 作者姓名： | 李龙彪 吴剑娇 陈仁尔 周其忠 徐土根 蒋华江 |
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| 作者单位： | 1. 台州学院化学系,浙江台州,317000
2. 杭州师范大学材料与化学化工学院,浙江杭州,310036 |
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| 基金项目： | 国家自然科学基金资助项目(21172166);浙江省自然科学基金资助项目(Y4100783);浙江省教育厅科研计划资助项目(20061048) |
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| 摘 要： | 以FeCl3为催化剂,L-脯氨酸为配体,以K2CO3为碱,在氮气的保护下在乙二醇二甲醚中回流,有效促进了溴代芳烃和取代硫酚的偶联反应生成相应的硫醚,产物的收率较高.
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| 关 键 词： | fecl3 l-脯氨酸 溴代芳烃 硫酚 偶联 |
Synthesis of diaryl thioethers from bromoarenes and substituted thiophenols catalyzed by FeCl3 |
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| LI Long-biao
,
WU Jian-jiao
,
CHEN Ren-er
,
ZHOU Qi-zhong
,
XU Tu-gen
,
JIANG Hua-jiang.Synthesis of diaryl thioethers from bromoarenes and substituted thiophenols catalyzed by FeCl3[J].Journal of Zhejiang University(Sciences Edition),2012,39(3):313-316. |
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| Authors: | LI Long-biao WU Jian-jiao CHEN Ren-er ZHOU Qi-zhong XU Tu-gen JIANG Hua-jiang |
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| Institution: | 1 (1.Department of Chemistry,Taizhou University,Taizhou 317000,Zhejiang Province,China;2.College of Material,Chemistry and Chemical Engineer,Hangzhou Normal University,Hangzhou 310036,China) |
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| Abstract: | Diaryl thioethers were effectively synthesized from coupling reaction of bromoarenes and substituted thiophenols with K2CO3 catalyzed by FeCl3 in the presence of L-proline at reflux in dimethoxyethane under nitrogen atmosphere. |
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| Keywords: | FeCl3 L-proline bromoarenes thiophenol coupling |
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