| 长链脂肪酸稀土络合体系的光致发光现象研究 |
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| 引用本文： | 李勇,张珂,黄保贵,徐怡庄,高宏成,吴瑾光. 长链脂肪酸稀土络合体系的光致发光现象研究[J]. 光谱学与光谱分析, 2002, 22(3): 353-356 |
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| 作者姓名： | 李勇 张珂 黄保贵 徐怡庄 高宏成 吴瑾光 |
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| 作者单位： | 北京大学化学与分子工程学院,北京,100871 |
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| 基金项目： | 国家重点基础研究发展规划项目 (G1 9980 61 30 7)，国家自然科学基金重大项目 (2 9992 530 )资助 |
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| 摘 要： | 本文合成了两烯长链脂肪酸和铕的二元配合物，进而以邻菲罗淋作为第二配体制得三元配合物，是很好的光致发光物质，元素分析及FTIR光谱初步确定了结构，分别为Eu(L1)32H2O,Eu(L1)3phen,Eu(L2)32H2O,Eu(L2)3phen(L1=月桂酸根、L2=硬脂酸根），长链脂肪酸通过羧酸双齿螯合配位，运用紫外吸收光谱和荧光光谱进一步讨论其发光机理。通过TEM电镜研究了配合物掺杂在高分子中的形貌与颗粒大小等分布情况。
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| 关 键 词： | 长链脂肪酸 稀土络合体系 铕配合物 光致发光 荧光光谱 FTIR TEM 发光性质 紫外吸收光谱 |
| 文章编号： | 1000-0593(2002)03-0353-04 |
| 修稿时间： | 2001-03-16 |
Study on the Photofluorescence of Eu(Ⅲ) and Long Chain Fatty Acid Complexes |
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| LI Yong,ZHANG Ke,HUANG Bao-gui,XU Yi-zhuang,GAO Hong cheng,and WU Jin guang College of Chemistry and Molecular Engineering,Peking University,Beijing ,China. Study on the Photofluorescence of Eu(Ⅲ) and Long Chain Fatty Acid Complexes[J]. Spectroscopy and Spectral Analysis, 2002, 22(3): 353-356 |
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| Authors: | LI Yong ZHANG Ke HUANG Bao-gui XU Yi-zhuang GAO Hong cheng and WU Jin guang College of Chemistry Molecular Engineering Peking University Beijing China |
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| Affiliation: | College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. |
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| Abstract: | The complexes having the compositions of Eu(L1)(3)2H2O,Eu(L1)3phen,Eu(L2)(3)2H2O,Eu(L2)3phen (phen = 1,10-phenathroline,L1 = Dodecanoic acid, L2 = Stearic acid) were synthesized and characterized by elemental analysis and FTIR spectra. Their fluorescence spectra, UV spectra and TEM (Transmission Electron Microscope) have been investigated. The results show that the 5D0-7F1 and 5D0-7F2 transition of Eu(III) are observed in the emission spectrum of the particles at room temperature. As good photoluminescent materials, they may be useful in the regions of EL (Electroluminescence) or macromolecule composite materials doped with rare earth. |
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| Keywords: | Photoluminescence FTIR Fluorescence spectra TEM |
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