Electronic structure and spin relaxation of Fe(III) in LiNbO3 |
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Authors: | H. -D. Pfannes A. Putzka J. F. Sampaio |
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Affiliation: | (1) Laboratorium für Angewandte Physik, Universität Duisburg, D-4100 Duisburg, FRG;(2) Dep. de Física, Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, Brazil |
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Abstract: | Crystal field parameter have been determined from EPR spectra (77K) of LiNbO3Fe(III). Anomalous line shapes are described phenomenologically and saturation studies are compared with calculations using a second order dynamic spin-hamiltonian H. Mössbauer spectra of LiNbO3Fe(III) have been interpreted by means of simulations using Liouville superoperators including a static fine-and a hyperfine spin-hamiltonian and H. Calculations have been performed using an effective spin of 1/2, the supermatrix with dimension 288 and a reduced formalism (supermatrix with dimension 96). |
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