Induced Alkene Reactions with Sulfur Dichloride. System Sulfur Dichloride-Dimethyl Sulfide as a Reagent for Polysulfonation and Conjugate Chlorination of Alkenes |
| |
| Authors: | Bodrikov I. V. Sazhin A. A. Shebelova I. Yu. Subbotin A. Yu. Rybalova T. V. Gatilov Yu. V. Barkhash V. A. |
| |
| Affiliation: | (1) Nizhegorodskii State Technical University, Nizhni Novgorod, 603024, Russia;(2) Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090, Russia |
| |
| Abstract: | In reaction of unsaturated compounds with sulfur dichloride in the presence of dimethyl sulfide radically new induced directions are realized: the reagent is involved as dimer or trimer (formation of di- and trisulfides). Alongside this process a conjugate chlorination occurred with participation of external nucleophiles, dimethyl sulfide and acetonitrile, furnishing sulfonium chlorides and N-substituted acetamides respectively. The relative importance of these alternative reactions depends on solvent, alkene structure, and order of reagents addition. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
