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Acoustic vibrations of embedded spherical nanoparticles
Authors:Daniel B. Murray  Lucien Saviot
Affiliation:aDepartment of Physics and Astronomy, Okanagan University College, Kelowna, British Columbia, Canada V1V 1V7;bLaboratoire de Recherche sur la Réactivité des Solides, UMR 5613 CNRS—Université de Bourgogne, Dijon, France
Abstract:A solid-matrix-embedded spherical nanoparticle has acoustic vibrational frequencies which are shifted and damped relative to modes of a free sphere. Not only the longitudinal plane wave acoustic impedances, but also the Poisson ratios of nanoparticle and matrix are important in determining the Q-factor of the “breathing” mode, for which frequencies and Q-factors with different material combinations are presented. High matrix sound speed (e.g. silica, titania, alumina, diamond) increases Q.
Keywords:Nanoparticles   Phonons   Matrix   Raman scattering
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