Crystal structure of polynuclear pivalate Ni(II) complexes with butanediol |
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| Authors: | G. V. Romanenko O. V. Kuznetsova E. Yu. Fursova V. I. Ovcharenko |
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| Affiliation: | 1. Institute of the International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
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| Abstract: | Using single crystal X-ray diffraction the structure of polynuclear [Ni6(OH)4(Piv)7(HOC4H8O)(HPiv)4], {K4[Ni12(CO3)2(Piv)16(OH)8(HOC4H8OH)2]}HPiv, {[Ni6(OH)4(Piv)6(HOC4H8O)(Me2CO)(HOC4H8OH)2]4×(Piv)4}, and {K[Ni2L2(Piv)3]}∞ complexes, where HOC4H8OH is 1,4-butanediol, HPiv is pivalic acid, and L is the anion of nitroxyl radical 2,2,5,5-tetramethyl-4-(3′,3′,3′-trifluoro-2′-oxy-1′-propenyl)-3-imidazolin-1-oxyl is determined. |
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