Chemical polarization of nuclei |
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| Authors: | D. G. Pobedimskii A. D. Pershin Sh. A. Nasybullin A. L. Buchachenko |
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| Affiliation: | 1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow
2. S. M. Kirov Kazan' Chemicotechnological Institute, USSR
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| Abstract: | | 1. | In the reaction of hydroperoxides with phosphites, catalyzed by vanadyl acetylacetonate, chemical polarization of31P nuclei (CPN) is suppressed or greatly weakened. | | 2. | The results of CPN-31P in the presence of a catalyst confirm the occurrence of the reaction of hydroperoxide with phosphites according to two pathways — radical and nonradical. The reaction of hydroperoxide with phosphites catalyzed by vanadyl acetylacetonate proceeds according to a nonradical mechanism. |
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