| RAFT Miniemulsion Polymerization of MMA with Cumyl Dithiobenzoate as Chain Transfer Agent |
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| 作者姓名： | Tian Ying GUO Dong Lin TANG Jing Wei ZHU Mou Dao SONG Bang Hua ZHANG |
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| 作者单位： | Tian Ying GUO，Dong Lin TANG，Jing Wei ZHU，Mou Dao SONG，Bang Hua ZHANG Key Laboratory of Functional Polymer Materials，Ministry of Education，Institute of Polymer Chemistry，Nankai University，Tianjin 300071 |
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| 摘 要： | As a kind of living free radical polymerizations, reversible addition-fragmentation chain transfer (RAFT) has been proved to be an important technique nowadays as it is applicable to a wide range of monomers at a wide range of temperature below 100oC. In …
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| 关 键 词： | RAFT聚合 微乳液 链转移剂 枯二硫代苯甲酸 甲基丙烯酸甲酯 |
| 收稿时间： | 2006-03-03 |
RAFT Miniemulsion Polymerization of MMA with Cumyl Dithiobenzoate as Chain Transfer Agent |
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| Tian Ying GUO Dong Lin TANG Jing Wei ZHU Mou Dao SONG Bang Hua ZHANG.RAFT Miniemulsion Polymerization of MMA with Cumyl Dithiobenzoate as Chain Transfer Agent[J].Chinese Chemical Letters,2006,17(9):1247-1250. |
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| Authors: | Tian Ying GUO Dong Lin TANG Jing Wei ZHU Mou Dao SONG Bang Hua ZHANG |
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| Abstract: | Reversible addition-fragmentation transfer (RAFT) miniemulsion polymerizations for PMMA with cumyl dithiobenzoate (CDB) as a chain transfer agent (CTA) has been carried out. Higher temperature made the polymerization much faster and the PDI remained below 1.20, when the temperature was upon 70 oC. |
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| Keywords: | RAFT polymerization miniemulsion chain transfer agent cumyl dithiobenzoate |
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