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Alkylation of the isosteviol terpenoid and its oxime with dibromoalkanes in the KOH-DMSO system |
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| Authors: | O. V. Andreeva O. I. Militsina G. I. Kovylyaeva M. G. Korochkina I. Yu. Strobykina G. A. Bakaleinik V. A. Al’fonsov V. E. Kataev R. Z. Musin |
| Affiliation: | (1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, Tatarstan, 420088, Russia |
| Abstract: | The reaction of 16-hydroximinoisosteviol with dihaloalkanes in the KOH-DMSO results in coupling of two isosteviol carcasses by the carboxy groups. The same products were previously synthesized by hydroximination of isosteviol diesters. |
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