The reaction mechanism of the perezonepipitzol transformation |
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| Authors: | P Joseph-Nathan V Mendoza E García |
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| Institution: | Departamento de Química del Centro de Investigación y de Estudios Avanzados, Instituto Politécnico Nacional, P.O. Box 14-740, México 14, D.F., México |
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| Abstract: | Regioselective deuterium labeling of perezone (1a) allows to establish that its transformation into the mixture of pipitzols (2a and 3a) takes place in a concerted process, as deduced from PMR measurements. |
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