Durch wasserstoff-transfer induzierte radikal-eliminierungen aus ortho-substituierten benzoesäuremethylestern |
| |
| Authors: | Ferdinand Bohlmann Rupert Herrmann Helmut Schwarz Hans-Martin Schiebel Norbert Schróder |
| |
| Institution: | Institut für Organische Chemie der Technischen Universität Berlin, D 1000 Berlin12, Straße des 17. Juni 135, West Germany;Institut für Organische Chemie der Technischen Universität Braunschweig, D 3300 Braunschweig, Schleinitzstr., West Germany;Gesellschaft für Molekularbiologische Forschung GmbH, D 3300 Braunschweig, Mascheroder Weg 1, West Germany |
| |
| Abstract: | The investigation of some 2H-labelled compounds as well as the analysis of energetic properties (appearance potential measurement, kinetic energy release) reveal some unusual elimination of radicals (CH3., OH. resp. CHO.) from ortho substituted bencoic acid methyl esters. It can be shown that most of the reactions are induced by a novel hydrogen transfer to the carboxyl function. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
