Derivatives and reactions of glutacondialdehyde IV 1-substituted-3-formyl-2(1)-pyridinethiones |
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Authors: | J Becher EG Frandsen |
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Institution: | Department of Chemistry, Odense University, DK-5000 Odense, Denmark |
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Abstract: | The reaction of the glutacondialdehyde anion with alkyl and acyl isothiocyanates has been investigated. Whereas alkyl isothiocyanates give rise to 1-alkyl-3-formyl-2(1)-pyridinethiones, -acylated glutacondialdehyde derivatives are formed from acyl isothiocyanates in most cases. The reaction courses may be understood on the basis of the principle of hard and soft acids and bases. |
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