An approach to natural 2-alkyl-6-methylpiperidines via N-acyllactam rearrangement |
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| Authors: | R.K. Hill T. Yuri |
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| Affiliation: | Department of Chemistry, University of Georgia, Athens, Ga 30602, U.S.A. |
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| Abstract: | Application of the Mundy N-acyllactam rearrangement to 6 - methyl - 2 - piperidone has led to a synthesis of optically active dihydropinidine, confirming the absolute configuration of the pine alkaloid pinidine, and to a new synthesis of the fire ant toxin, Solenopsin A. |
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