| 8-氨基喹啉取代苯甲酰胺衍生物对汞离子和铜离子的识别 |
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| 引用本文： | 吴粦华,韩莉峰,阮艺斌,江云宝. 8-氨基喹啉取代苯甲酰胺衍生物对汞离子和铜离子的识别[J]. 分析化学, 2010, 38(1) |
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| 作者姓名： | 吴粦华 韩莉峰 阮艺斌 江云宝 |
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| 作者单位： | 1. 龙岩学院化学与材料工程系,龙岩,364000
2. 厦门大学化学化工学院化学系现代分析科学教育部重点实验室,厦门,361005 |
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| 基金项目： | 国家自然科学基金(No.20675069)资助项目 |
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| 摘 要： | 设计合成了可识别金属离子的荧光传感分子8-氨基喹啉取代苯甲酰胺衍生物,通过核磁共振谱和质谱表征其结构;利用其光谱性质研究了该系列物质对过渡金属离子Cu2+,Hg2+,Pb2+,Zn2+,Ni2+和Cd2+的识别性质,初步探讨了其识别机理。实验表明:在乙腈中,8-氨基喹啉苯甲酰胺的吸收光谱在509nm处对Cu2+有响应,溶液由无色变成红色;而其荧光光谱对Hg2+和Cu2+有良好的选择性,荧光增强倍率分别高达368和192,与金属离子形成结合比为1:1配合物。
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| 关 键 词： | 8-氨基喹啉取代苯甲酰胺衍生物 吸收光谱 荧光增强 铜 汞 分子识别 |
Recognition of Mercury Ion and Copper Ion with 8-Aminoquinoline Derivatives |
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| WU Lin-Hua,HAN Li-Feng,RUAN Yi-Bin,JIANG Yun-Bao. Recognition of Mercury Ion and Copper Ion with 8-Aminoquinoline Derivatives[J]. Chinese Journal of Analytical Chemistry, 2010, 38(1) |
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| Authors: | WU Lin-Hua HAN Li-Feng RUAN Yi-Bin JIANG Yun-Bao |
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| Affiliation: | Department of Chemical and Materials Engineering;Longyan University;Longyan 364000;Department of Chemistry;College of Chemistry and Chemical Engineering;the Ministry of Education Key Laboratory of Analytical Sciences;Xiamen University;Xiamen 361005 |
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| Abstract: | The novel 8-Aminoquinoline(8-AQ) derivatives receptor was designed and synthesized.Its structure was characterized by NMR and ESI-MS.It was investigated to recognize metal ions such as Cu2 +,Hg2 +,Pb2 +,Zn2 +,Ni2 + and Cd2 + via its absorption and fluorescence spectra.The recognition mechanism and binding mode were discussed.The results showed that 8-AQ derivatives 1 coordinated with Cu2 + can induce a new absorption peak at 509 nm,which turned the solution to red from colorless.In acetonitrile Hg2 + and Cu... |
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| Keywords: | 8-Aminoquinoline derivatives Absorption spectra Fluorescence enhancement Copper Mercury Molecular Recognition |
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