Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene |
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| Authors: | Xu Liang Shi Yian |
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| Institution: | Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA. |
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| Abstract: | Studies show that a variety of conjugated dienes and triene can be enantioselectively diaminated using di-tert-butyldiaziridinone as nitrogen source and chiral N-heterocyclic carbene-Pd(0) complex as catalyst in good enantioselectivity (62-91% ee) with high regio- and diastereoselectivity. |
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