Kinetics and mechanism of the catalytic epoxidation of cyclohexene with tert-butyl hydroperoxide in the presence of molybdenum–squarate complex |
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| Authors: | Encho H Balbolov Stefan V Kotov Tsonko M Kolev and Mariana G Topuzova |
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| Institution: | (1) University “Prof. Dr. As. Zlatarov”, Bourgas, Bulgaria;(2) Institute of Organic Chemistry, Bulgarian Academy of Sciences, Sofia, Bulgaria |
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| Abstract: | The kinetics of the catalytic epoxidation of cyclohexene with tert-butyl hydroperoxide (TBHP) in the presence of a novel molybdenum–squarate complex was studied. Both the kinetics and mechanism
of the process were found to be similar to those established with the “classical” homogeneous catalysts for epoxidation. |
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| Keywords: | Epoxidation Cyclohexene Molybdenum– squarate complex Catalyst |
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