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Synthesis and characterization of a-{3-[(2,3-dihydroxy) propoxy]propyl}-v-butyl-polydimethylsiloxanes
Authors:Xiao Li Zhan  Zhen Huan Luo  Qing Hua Zhang  Bi Chen  Feng Qiu Chen
Affiliation:Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China
Abstract:Hydrosilylation has been carried out between Si-H terminated polydimethylsiloxanes with narrow molecular weight distribution and protected 3-allyloxy-1,2-propanediol, and after subsequently alcoholyzed, α-{3-[(2,3-dihydroxy)propoxy]propyl}-ω-butyl-polydimethylsiloxanes with varying number of ((Si(CH3)2-O) unit were obtained. At each step, the produced compounds were carefully characterized. The results showed that each step was successfully carried out and target products were achieved.
Keywords:Polydimethylsiloxane  Anionic ring-opening polymerization  Hydrosilylation  Alcoholysis  
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