| 双官能团醇类化合物催化胺化反应的研究进展 |
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| 引用本文： | 白国义,陈立功. 双官能团醇类化合物催化胺化反应的研究进展[J]. 化学进展, 2005, 17(2): 0-298 |
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| 作者姓名： | 白国义 陈立功 |
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| 作者单位： | 天津大学药物科学与技术学院,天津,300072;河北大学化学与环境工程学院,保定,071002;天津大学药物科学与技术学院,天津,300072 |
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| 基金项目： | 国家自然科学基金资助项目 (No.2 0 376 0 5 7) |
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| 摘 要： | 本文综述了由双官能团醇类化合物催化胺化合成二元胺或环胺的研究进展,分别讨论了金属催化剂和固体酸催化剂对双官能团醇类化合物的不同作用机制,考察了反应物结构对 反应活性和选择性的影响,重点介绍了超临界氨流体在二元醇催化胺化反应中的应用,并指出了今后研究的方向.
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| 关 键 词： | 双官能团醇类化合物 二元胺 环胺 催化胺化 超临界氨流体 |
| 文章编号： | 1005-281X(2005)02-0293-06 |
| 收稿时间： | 2004-02-01 |
| 修稿时间： | 2004-02-01 |
Progress in the Catalytic Amination of Bifunctional Alcohols |
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| Bai Guoyi,Chen Ligong. Progress in the Catalytic Amination of Bifunctional Alcohols[J]. Progress in Chemistry, 2005, 17(2): 0-298 |
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| Authors: | Bai Guoyi Chen Ligong |
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| Affiliation: | 1.College of Pharmaceuticals and Biotechnology, Tianjin University,Tinajin 300072,China2.College of Chemistry and Environmental Science, Hebei University,Baoding 071002,China |
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| Abstract: | The progress in the catalytic amination of bifunctional alcohols to diamines or cyclic amines is reviewed in this paper. The different catalytic mechanisms of metal catalysts and solid acids are discussed respectively. The relationship between the structures of bifunctional alcohols and the reaction results is examined. Application of supercritical ammonia in the catalytic amination of diols is intensively introduced. The further research trends are pointed out. |
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| Keywords: | bifunctional alcohols diamines cyclic amines catalytic amination supercritical ammonia |
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