Stereoselective synthesis of 2,2-bis(C-branched-chain)glucopyranosid-3-ulose via an autoxidation-Michael addition reaction |
| |
| Authors: | Liu Hong-Min Zhang Fuyi Zou Da-Peng |
| |
| Affiliation: | Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, PR China. liuhm@zzu.edu.cn |
| |
| Abstract: | 2,2-Bis(C-branched-chain)glucopyranosid-3-uloses, designed for the preparation of biologically active natural product iridoid derivatives, are synthesized selectively by the new reaction of butenolide-containing sugar with active methylene compounds, and the new reaction is clarified as autoxidation followed by Michael addition of carbanion. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
