Synthesis and structure of [[MeAl(mu-PMes)(PMes)]2Li4]2 x 7thf,containing a [MeAl(mu-PMes)(PMes)]2(4-) tetraanion (Mes = 2,4,6-Me3C6H2) |
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| Authors: | García Felipe Haigh Robert McPartlin Mary Wright Dominic S |
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| Institution: | Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW. |
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| Abstract: | The reaction of MeAlCl2 with MesPHLi (1:4 equivalents) in thf/toluene gives the cage complex MeAl(mu-PMes)(PMes)]2Li4]2 x 7thf (1), containing an MeAl(mu-PMes)(PMes))2]4- tetraanion which is valence-isoelectronic with extensively studied Group 15 anions of the type E(mu-NR)(NR)]2(2-). |
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