Green oxidation with aqueous hydrogen peroxide |
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Authors: | Noyori Ryoji Aoki Masao Sato Kazuhiko |
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Affiliation: | Department of Chemistry and Research Center for Materials Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. noyori@chem3.chem.nagoya-u.ac.jp |
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Abstract: | Aqueous H2O2 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogensulfate as an acidic phase-transfer catalyst. It oxidizes alcohols, olefins, and sulfides under organic solvent- and halide-free conditions in an economically, technically, and environmentally satisfying manner. |
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