A facile and novel route to unprecedented manganese C4 cumulenic complexes |
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| Authors: | Venkatesan Koushik Fernández Francisco J Blacque Olivier Fox Thomas Alfonso Montserrat Schmalle Helmut W Berke Heinz |
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| Affiliation: | Anorganisch-Chemisches Institut der Universit?t Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland. |
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| Abstract: | The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe) [=C=C=C=C(SnPh3)2] was obtained by photolysis of the C(sp2)-Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh3)-C[triple bond]CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H8) and Ph3Sn-C4-SnPh3. |
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