Homoatomic P --> P coordination: a versatile synthetic approach to polyphosphorus dications |
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Authors: | Burford Neil Ragogna Paul J McDonald Robert Ferguson Michael J |
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Affiliation: | Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, B3H 4J3, Canada. Neil.Burford@dal.ca |
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Abstract: | Polyphosphorus dications have been synthesised and comprehensively characterised as diphosphine (dppe, dmpe and dpph) linked Ar2P+ Lewis acids (Ar = C6H5); this application of unique homoatomic coordination chemistry provides important building blocks for extended systems. |
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