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A facile tetrahydrothiophene-catalyzed ylide route to vinyloxiranes
Authors:Li Kai  Deng Xian-Ming  Tang Yong
Affiliation:Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 354 Fenglin Lu, Shanghai 200032, China.
Abstract:Access to vinyloxiranes using aldehydes and allylic bromides in the presence of 1-5 mol% tetrahydrothiophene is reported. Both aliphatic and aromatic aldehydes work well in this reaction and the catalyst loading could be reduced as low as 0.5 mol%.
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