Oxygen adsorption on stepped Pd(100) surfaces |
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Authors: | F. Li F. Allegretti S. Surnev F.P. Netzer Y. Zhang W.-B. Zhang K. Reuter |
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Affiliation: | 1. Institute of Physics, Surface and Interface Physics, Karl-Franzens University Graz, A-8010 Graz, Austria;2. Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany;3. Technische Universität München, Lichtenbergstr. 4, D-85747 Garching, Germany |
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Abstract: | We use scanning tunneling microscopy (STM) and high-resolution core-level spectroscopy (XPS) measurements to study the initial oxidation of vicinal Pd(100) surfaces exhibiting close-packed (111) steps. The XPS data analysis is supported by detailed surface-core level shift calculations based on density-functional theory. Both STM images and the XPS spectra are found to be perfectly consistent with a characteristic zigzag O decoration of the Pd steps predicted by a preceding cluster-expansion based theoretical study [Y. Zhang and K. Reuter, Chem. Phys. Lett. 465, 303 (2008)]. Continued oxygen uptake leads to the additional stabilization of a p(2 × 2)-O overlayer on the Pd(100) terraces, and ultimately to step bunching with the resulting large Pd(100) terraces covered by the PdO(101) surface oxide. |
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