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Influence of B2O3 on electrical properties and phase transition of lead-free Ba(Ti0.9Sn0.1)O3 ceramics
Authors:N. Tawichai  U. Intatha  S. Eitssayeam  K. Pengpat  T. Tunkasiri
Affiliation:1. Faculty of Science, Department of Physics , Chiang Mai University , Chiang Mai 50200, Thailand;2. School of Science, Mae Fah Luang University , Chiang Rai 57000, Thailand
Abstract:The phase transition and electrical properties of Ba(Ti0.9Sn0.1)O3 ceramics with B2O3 added were investigated to explore the effect of B2O3 addition on enhanced densification and dielectric constant of these ceramics. With increasing B2O3 content, a linear reduction of ferroelectric to paraelectric transition temperature was observed. In addition, higher B2O3 concentrations enhanced a ferroelectric relaxor behavior in the ceramics. Changes in this behavior were related to densification, second-phase formation and compositional variation of the ceramics.
Keywords:phase transition  dielectric properties  ceramics  sintering
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