Relaxation Dynamics In Photo-Excited Halogen-Bridged Pt-Complexes Studied By Femtosecond Luminescence Spectroscopy |
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Authors: | T. Suemoto S. Tomimoto |
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Affiliation: | Institute for Solid State Physics , The University of Tokyo , Kashiwanoha 5-1-5, Kashiwa-shi , 277-8581 , Japan |
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Abstract: | The ultrafast dynamics of excited electronic states in a series of quasi-one-dimensional halogen-bridged platinum-complexes was investigated by using femtosecond luminescence spectroscopy. In Pt-Br system, the wave-packet oscillation of the local vibration of self-trapped excitons (STEs) was observed. The time evolutions of luminescence intensity in Pt-Br and Pt-Cl were successfully described by using a model based on a wave-packet motion on the interaction mode coordinate. In Pt-I, very fast decay was observed, suggesting the existence of efficient non-radiative decay channel directing to structural change. |
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Keywords: | Platinum-complex Self-trapped Exciton Structural Change Wave-packet |
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